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MGO% SiO2% CaO% LOI%
<*5 <1 <1.5
<3
<*4 <2 <2
<4
<*2 <3 <2
<5
<*0 <4 <2
<6
<*7 <5 <3
<7
<*5 <6 <3
<8
<*0 <8 <3
<*0
Magnesium oxide, or magnesia, is a white solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO. It is formed by an ionic bond between one magnesium and one oxygen atom. Magnesium oxide is hygroscopic in nature and care must be taken to protect it from moisture. Magnesium hydroxide forms in the presence of water (MgO + H2O -Mg(OH)2), but it can be reversed by heating it to separate moisture.
Magnesium oxide was historically known as magnesia alba (literally, the white mineral from Magnesia), to differentiate it from magnesia negra, a black mineral containing what is now known as manganese.
Applications
A refractory material is one that is physically and chemically
stable at high temperatures. "By far the largest consumer of
magnesia worldwide is the refractory industry, which consumed
about *6% of the magnesia in the United States in ***4, the
remaining *4% being used in agricultural, chemical, construction,
environmental, and other industrial applications.
Cement
MgO is one of the raw materials for making Portland cement in dry
process plants. If too much MgO is added, the cement may become
expansive. Production of MgO-based cement using serpentinite and
waste CO2 (as opposed to conventional CaO-based cement using
fossil fuels) may reduce anthropogenic emissions of CO2.
Desiccant
MgO is an efficient moisture absorbent used by many libraries for
preserving books.
Medical
In medicine, magnesium oxide is used for relief of heartburn and
sore stomach, as an antacid, magnesium supplement, and as a
short-term laxative. It is also used to improve symptoms of
indigestion. Side effects of magnesium oxide may include nausea
and cramping. In quantities sufficient to obtain a laxative
effect, side effects of long-term use include enteroliths
resulting in bowel obstruction.
Other
MgO is used as an insulator in industrial cables, as a basic
refractory material for crucibles and as a principal fireproofing
ingredient in construction materials. As a construction material,
magnesium oxide wallboards have several attractive
characteristics: fire resistance, moisture resistance, mold and
mildew resistance, and strength.
It is used as a reference white color in colorimetry, owing to
its good diffusing and reflectivity properties. It may be smoked
onto the surface of an opaque material to form an integrating
sphere.
It is used extensively in electrical heating as a component of
"CalRod"-styled heating elements. There are several mesh sizes
available and most commonly used ones are *0 and *0 mesh per the
American Foundry Society. The extensive use is due to its high
dielectric strength and average thermal conductivity. MgO is
usually crushed and compacted with minimal airgaps or voids. The
electrical heating industry also experimented with aluminium
oxide, but it is not used anymore.
Pressed MgO is used as an optical material. It is transparent
from 0.3 to 7 μm. The refractive index is 1.*2 at 1 μm and the
Abbe number is *3.*8. It is sometimes known by the Eastman Kodak
trademarked name Irtran*5, although this designation is long
since obsolete. Crystalline pure MgO is available commercially
and has small use in infrared optics.
It is packed around transuranic waste at the Waste Isolation
Pilot Plant, to control the solubility of radionuclides.
An aerosolized solution of MgO is used in library science and
collections management for the deacidification of at-risk paper
items. In this process, the alkalinity of MgO (and similar
compounds) neutralizes the relatively high acidity characteristic
of low-quality paper, thus slowing the rate of deterioration.
It is also used as a protective coating in plasma displays.
Precautions
Magnesium oxide is easily made by burning magnesium ribbon which
oxidizes in a bright white light, resulting in a powder. However,
the bright flame is very hard to extinguish and it emits a
harmful intensity of UV light. Inhalation of magnesium oxide
fumes can cause metal fume fever.
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Model No: | top103 |
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