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HDPE is known for its large strength to density ratio. The mass
density of high-density polyethylene can
range from 0.*3 to 0.*7 g/cm3. Although
the density of HDPE is only marginally higher than that of
low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile
strength than LDPE. The difference in strength exceeds the
difference in density, giving HDPE a
higher specific strength. It is also
harder and more opaque and can withstand
somewhat higher temperatures (**0 °C/ **8 °F for short periods, **0
°C /**0 °F continuously). High-density polyethylene, unlike
polypropylene, cannot withstand normally
required autoclaving conditions. The
lack of branching is ensured by an appropriate choice of
catalyst(e.g., Ziegler-Natta catalysts) and reaction
conditions.
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