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Potassium osmate (VI) dehydrate is an inorganic compound with the
formula H4K2O6Os. ISn the VI (6+) oxidation state the compound is a
diamagnetic purple salt contains osmium. It is soluble in water and
slowly decomposes in aqueous solution. Potassium osmate (VI)
dehydrate is insoluble in ethereal and alcoholic
solvents.
Potassium osmate (VI) dehydrate is used as a catalyst in the
dihydroxylation of cyclic internal alkenes such as lactams, 1,2
dioxines dihydrothiophenes and hexahydropyrans. The resulting diols
from such reactions have been used in the preparation of various
carbohydrate and similar molecular scaffolds. Potassium osmate (VI)
dehydrate iss also used in the development of an asymmetric
dihydroxylation methodology targeting heteroaromatic
acrylates.
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