Product Description
MATERIAL SAFETY DATA SHEET R**4a PRODUCT AND COMPANY
IDENTIFICATION Product name: 1,1,1,*-Tetrafluoroethane Synonyms:
HFC***4a, refrigeration gas (R**4a) Supplier: Zhejiang ze China
fluorine chemical Co., LTD. COMPOSITION/ INGREDIENTS PURITY ( √ )
MIXTURE ( ) Material Name: 1,1,1,*-Tetrafluoroethane Content Wt:
*9.9% CAS No.: *******2 HAZARDS IDENTIFICATION Hazards Class: 2.2
Non Flammable Gas Invasive routes: inhalation, ingestion, eye and
skin Potential health effects: High concentration of vapor in air
will reduce the oxygen and cause anoxic asphyxiation. Eye/skin
contact with liquid may cause frostbite or other harms. Under
high temperature (like fire or on the surface of hot metal) will
decompose and forming toxic materials like hydrochloric,
hydrofluoric acid and carbonyl halides. Environment effects: The
potential ODP=0, GWP=***0. Flame effects: Under common
situation(common tempreture and atmospheric pressure) ,this
product is non-flammable, but under certain situation it will .
FIRST AID MEASURES Skin: In case of contact, take off the
polluted clothes, flush area with suds water and clean water at
least *5 minutes, do not use hot water, call a physician. Eyes:
In case of contact, flush with plenty of clean water or
physiological saline, call a physician. Inhalation: If inhaled,
immediately remove to fresh air. Keep respiratory tract fluntely.
If have difficulty in breathing, give an oxgen therapy. If not
breathing, give artificial respiration or closed cardiac massage
at once. Call a physician. Ingestion: Not a probable rout, owever
in case of accident ingestion, drink plenty of lukewarm water,
make emetic action, call a physician. 5 FIRE-FIGHTING MEASURES
Flammable characteristics: It is not flammable and explosive in
the air. In case of phyrogenetic decomposition, it will form
toxic materials like hydrochloric, hydrofluoric acid and carbonyl
halides. In case of meeting hihg tempreature, the inner pressure
of the container strengthen and may cause craze and explosion.
Harmful combustion products: Forming toxic materials like
hydrochloric, hydrofluoric acid and carbonyl halides.
Fire-fighting ways: Cut off the gas origin, use water spray or
fog to cool the container, remove the container to clean place if
possible. Extinguish agent: Roridous water, foam, carbon dioxide.
Extinguish notices and measures: Wear specialized protective suit
and self-contained breathing apparatus(SCBA), and to extinguish
the fire on the upper wind position. 6 ACCIDENTAL RELEASE
MEASURES Remove the staffs from the release polluted places to
upper wind position, and isolote the staffs and the polluted
zone, control the passes. The handling personnel had better to
wear specialized protective suit and self-contained breathing
apparatus(SCBA), find out the release source and cut off it, and
remove the released container to ventilate area and keep
ventilation. The leaked container should be dealt with properly.
Use after repairing and checking. Eliminate way: Keep ventilation
and accelerating spread. If possible, use the gas into production
immediately. 7 HANDLING AND STORAGE Hadling: Keep ventilation and
airtight producing procedure. The operators must have
professional training and obey the operation rules strictly.
While the consistency in the air surpass the standard
consistency, the handling personnel have to wear self-contained
breathing filtermask(half-mask respirator) and chemical
protective goggles. Prevening the gas leak out to the workplace’s
air. Gently handling to avoid the damage of the container or its
accessories. To equip the relevant emergency equipment. Storage:
Keep in cool, ventilated places. Keep far away from fire, hot
source. The storage places?tempreature should lower than *0℃,
avoid direct sunlight. And separated with inflammables, oxidizer,
edible chemicals, do not have a mix storage. Storage place should
have emergency release handling equipment. Notice the chemical
name while checking and accepting, note the checking date, use
them orderly. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION The max
consistency: China MAC (mg/m3): No data. China PC—TWA (mg/m3): No
data. China PC—STEL (mg/m3): No data Former Soviet Union MAC
(mg/m3): No data USA TLV-TWA: No data USA TLV-STEL: No data
Monitor way: gas phase chromatography. Engineering control:
airtight producing procedure, good ventilation. Respiratory
system protection: While the consistency in the air surpass the
standard consistency, the handling personnel have to wear
self-contained breathing filtermask(half-mask respirator). Eyes
protection: wear chemical protective goggles when necessary.
Personnel protection: wear general job protective suit. Hands
protection: wear general job protective gloves. Others: avoid
high consistency inhalation. Under the monitor while working in
the container,restricted area and other high consistency area. 9
PHYSICAL PROPERTIES Appearance and characteristics: colorless
transparency liquid, gas with slight aetheral odor. PH Index: No
data. Melting point (℃): No data. Boiling point (℃): **1.6℃
Freezing point(℃): ***1℃(℃) Liquid density: ***6 kg/m3 (*5℃)
Saturation vapor density: 5.*5 kg/m3 Saturation vapor
pressure(kPa): No data. Critical tempreature (K): **4.*5 Critical
pressure(MPa): 4.*6 Flash point(℃): insignificance Inflame
temperature(℃): insignificance UEL[% (V/V)]: insignificance LEL[%
(V/V)] : insignificance Solubility: slight solubilize in water,
solubilize in ethanol, ether. Main use: refrigerant agent,
plastic vesicant, medicine, makeup aerosol, medical inhalator
propellant etc. *0 STABILITY AND REACTIVITY Stability: stable The
condition to be avoided: high temperature Incompatibility with
other material: alkali or alkaline earth metal-powdered Al, Zn,
Be etc. Polymerization: will not occur Decomposition: forming
toxic materials like hydrochloric, hydrofluoric acid and carbonyl
halides. *1 TOXICOLOGICAL INFORMATION Virulent LD*0: No data.
LC*0: No data. Thrill: No data. *2 ECOLOGICAL INFORMATION
Ecotoxity: No data. Biological degradability: No data.
Non-biological degradability: No data. *3 DISPOSALE CONSIDERATION
Waste disposal: mix with the other fuels before burning, be
careful to form phosgene during the burning. The halogen hydride
discharged from incinerator should be cleaned by acid. Notice:
the disposal should comply with local regulation. *4
TRANSPORTATION INFORMATION Hazard class: 2.2 UN No.: ***9 Package
lable: non-flammable gas Package classification: III Package:
steel cylinder, ampoule bottle with common wooden case outside.
Notice: while transported in steel cylinders, make sure the
cylinders?safety cap are fixed. Cylinders shouldbe lied flat and
make the cylinders?mouth at the same directions. The height
should not surpass the vehicle’s fence board and fix with the
trigonal board to prevent the move of the cylinders. Mixture
transportation with edible chemicals is forbidden. During summer
the products should be transported in the morning or in the
evening and avoid direct sunshine. Should transport on certain
route during road transportation, never stop in residential area
or densely populated area. Humping is forbidden during railroad
transportation. *5 REGULATORY INFORMATION ‘REGULATIONS ON
SECURITY ADMINISTRATION OF DANGEROUS CHEMICAL GOODS?( Rule No.
**4, stated by State Council, China, carry into execution from
Mar. *5, ***2 ); ‘REGULATIONS ON CHEMICALS?SAFETY USE IN
WORKPLACE?Rule No. **3, stated by employment department,
China)etc. have made a series of relevant rules including the
use, producing, storage, transportation, loading and unloading.
According to GB *******2 Standard of Republic of China ,its
dangerous classification is 2.2 non-flammable gas. This MSDS
obeys the Standard GB *********0. *6 OTHER INFORMATION
Country: |
China |
Model No: |
R134a
|
FOB Price: |
( Negotiable ) (Negotiable)
Get Latest Price
|
Place of Origin: |
china |
Price for Minimum Order: |
- |
Minimum Order Quantity: |
- |
Packaging Detail: |
13.6kg, 800kg/800L, 950kg/926L steel cylinders.Ã�ïÂ& |
Delivery Time: |
15 |
Supplying Ability: |
- |
Payment Type: |
T/T |
Product Group : |
- |